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  • 1 M. Curie-Skłodowska University Faculty of Chemistry, Department of Planar Chromatography M. Curie-Skłodowska Sq. 3 20-031 Lublin Poland
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The effect of electric fields on mobile phase migration velocity and on the retention of chromatographed solutes has been investigated for so-called horizontal electric fields with sample applied at the anode and cathode ends of the plates. An electric field can also affect the surfaces of stationary phases. These investigations were performed in a so-called vertical electric field at a gradient voltage 12 kV cm −1 . The effect of the electric field on the apolar component of the surface free energy was determined for six popular stationary phases; for silica and aluminum oxide it was possible to determine the acidic and basic components of the surface free energy. The effect of electric fields on the zeta potential of silica-methanol and aluminum oxide-water systems was also demonstrated.

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation
1988
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
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Address
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Springer Nature Switzerland AG
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ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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