JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 16: Issue 6
The effect of the substituents of β -ketoiminato ligand of copper(II) and nickel(II) complexes on their retention on thin layers of polyacrylonitrile
Authors:
Rada Baošić University of Belgrade Faculty of Chemistry Studentski trg 16 P.O. Box 158 11001 Belgrade, Serbia and Montenegro

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Dušanka Milojković-Opsenica University of Belgrade Faculty of Chemistry Studentski trg 16 P.O. Box 158 11001 Belgrade, Serbia and Montenegro

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Živoslav Tešić University of Belgrade Faculty of Chemistry Studentski trg 16 P.O. Box 158 11001 Belgrade, Serbia and Montenegro

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Pages:
412–416
Online Publication Date:
15 Mar 2007
Publication Date:
01 Dec 2003
Article Category:
Research Article
DOI:
https://doi.org/10.1556/jpc.16.2003.6.1
Keywords:
Thin-layer chromatography; Polyacrylonitrile adsorbent; β -Ketoiminato complexes; Ligand substituents
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The effect of substituents of the β -ketoiminato ligand of 24 copper(II) and nickel(II) complexes on hRF values obtained by TLC on polyacrylonitrile (PAN) has been studied. Chelate ligands were prepared by condensation of diamine (dm) and the corresponding β -diketone. Copper(II) and nickel(II) complexes with chelate ligands containing ethylenediamine (en = 1,2-diaminoethane) or propylene diamine (pn = 1,2-diaminopropane) as the amine part and acetylacetone (acac = 2,4-pentanedionato ion) and/or phenylacetylacetone (phacac = 1-phenyl-1,3-pentanedionato ion), and/or trifluoroacetylacetone (tfacac = 1,1,1-trifluoro-1,3-pentanedionato ion), i.e. phenylacetylacetone as β -diketone, were synthesized. Ten non-aqueous mobile phases (six mono-component and four two-component) and two aqueous mobile phases were used for chromatographic separation. The results revealed that the mobility of the complexes decreased on substitution of the CH 3 group in the β -ketoiminato ligand by CF 3 or C 6 H 5 . The chromatographic behavior of the complexes on PAN was compared with that on other adsorbents. Possible separation mechanisms are discussed.

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Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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