JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 18: Issue 105
Estimation of the hydrophobicity of tris-β-diketonato complexes from reversed-phase thin-layer chromatographic data
Authors:
Maja Natić University of Belgrade Faculty of Chemistry P.O. Box 158 11001 Belgrade Serbia and Montenegro

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Rada Baošić University of Belgrade Faculty of Chemistry P.O. Box 158 11001 Belgrade Serbia and Montenegro

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Dušanka Milojković-Opsenica University of Belgrade Faculty of Chemistry P.O. Box 158 11001 Belgrade Serbia and Montenegro

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Živoslav Tešić University of Belgrade Faculty of Chemistry P.O. Box 158 11001 Belgrade Serbia and Montenegro

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Pages:
344–348
Online Publication Date:
17 Mar 2007
Publication Date:
01 Oct 2005
Article Category:
Research Article
DOI:
https://doi.org/10.1556/jpc.18.2005.5.2
Keywords:
β-Diketonato complexes; Reversed-phase thin-layer chromatography; RP-18 silica; Lipophilicity
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Experimental RM values for two series of β-diketonato complexes, M(acac) 3- n (phacphac) n and M(acac) 3- n (phSacphSac) n , where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. RM0 values were determined for the different mobile phase mixtures by linear extrapolation to 0% ( v/v ) organic modifier. Lipophilicity C0 was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated C log P values.

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Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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