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Aleksandra Radoičić University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

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Helena Majstorović AIC Tamiš Novoseljanski put 33 26000 Pančevo Serbia

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Tibor Sabo University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

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Živoslav Tešić University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

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Dušanka Milojković-Opsenica University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

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The chromatographic behavior of twelve neutral, mixed cobalt(III) complexes of the uns-cis -edda-type has been investigated in six planar chromatographic systems. Four different stationary phases - unmodified silica gel, CN-silica, cellulose, and alumina - were combined with water-organic solvent (methanol or acetone) binary mobile phases. The effect of the water content of the mobile phases on retention of the complexes was investigation systematically. On the basis of the results obtained, possible separation mechanisms were considered. Hydrophilic-interaction chromatography was assumed to be the mechanism determining separation under normal-phase conditions, i.e. use of mobile phases containing small amounts of water. Reversed-phase chromatography occurs when water-rich mobile phases are used.

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation
1988
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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