JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 22: Issue 5
TLC retention behavior of brodifacoum, bromadiolone, and coumatetralyl and their impurities on different adsorbents
Authors:
Tomislav Tosti University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

Search for other papers by Tomislav Tosti in
Current site
Google Scholar
PubMed Close
,
Gordana Rakić University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

Search for other papers by Gordana Rakić in
Current site
Google Scholar
PubMed Close
,
Maja Natić University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

Search for other papers by Maja Natić in
Current site
Google Scholar
PubMed Close
,
Dušanka Milojković-Opsenica University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

Search for other papers by Dušanka Milojković-Opsenica in
Current site
Google Scholar
PubMed Close
,
Suren Husinec University of Belgrade Institute of Chemistry, Technology, and Metallurgy, Center for Chemistry Njegoševa 12 P.O. Box 815 11000 Belgrade Serbia

Search for other papers by Suren Husinec in
Current site
Google Scholar
PubMed Close
,
Vladimir Savić University of Belgrade Faculty of Pharmacy P.O. Box 146 Belgrade Serbia

Search for other papers by Vladimir Savić in
Current site
Google Scholar
PubMed Close
, and
Živoslav Tešić University of Belgrade Faculty of Chemistry P.O. Box 51 11158 Belgrade Serbia

Search for other papers by Živoslav Tešić in
Current site
Google Scholar
PubMed Close
Pages:
333–343
Online Publication Date:
20 Nov 2009
Publication Date:
01 Oct 2009
Article Category:
Research Article
DOI:
https://doi.org/10.1556/jpc.22.2009.5.4
Keywords:
Brodifacoum; Bromadiolone; Coumatetralyl; Lipophilicity
Restricted access

The chromatographic behavior of three biocidal technical materials, rodenticide active ingredients brodifacoum, bromadiolone, and coumatetralyl, and impurities present in the technical material was investigated by both normal-phase (NP) and reversed-phase (RP) planar chromatography. The research was carried out using thinlayers of silica gel, alumina, cellulose, and C 18 silica. Several solvents on their own or in various combinations and proportions were used for separation. The optimum chromatographic systems for separation of the substances from each other and from their impurities were selected. Under reversed-phase chromatographic (RPC) conditions a linear correlation between RM values and mobile phase composition was established. From results obtained, the lipophilicity RM ° and C0 were determined. Possible separation mechanisms are discussed on the basis of the established retention behavior.

  • W. Langseth, U. Nymoen , Fresenius J. Anal. Chem. 339 (1991) 249–252.

    Nymoen U. , '' (1991 ) 339 Fresenius J. Anal. Chem. : 249 -252 .

  • R.B. Mack. , N. C. Med. J. 55 (1994) 554–556.

    Mack R.B. , '' (1994 ) 55 N. C. Med. J. : 554 -556 .

  • B. Katona, S. Wason , J. Emerg. Med. 7 (1989) 627–631.

    Wason S. , '' (1989 ) 7 J. Emerg. Med. : 627 -631 .

  • R.A. Lipton, E.M. Klass , JAMA 252 (1984) 3004–3005.

    Klass E.M. , '' (1984 ) 252 JAMA : 3004 -3005 .

  • R.A. Helmuth, D.W. McCloskey, D.J. Doedens, D.A. Hawley , Lab. Med. 20 (1989) 25–27.

    Hawley D.A. , '' (1989 ) 20 Lab. Med. : 25 -27 .

  • W.A. Norcross, T.G. Ganiats, L.P. Ralph, R.G. Seidel, T.S. Ikeda , West J. Med. 159 (1993) 80–82.

    Ikeda T.S. , '' (1993 ) 159 West J. Med. : 80 -82 .

  • K. Hunter , J. Chromatogr. 321 (1985) 255–272.

    Hunter K. , '' (1985 ) 321 J. Chromatogr. : 255 -272 .

  • K. Hunter , J. Chromatogr. 270 (1983) 267–276.

    Hunter K. , '' (1983 ) 270 J. Chromatogr. : 267 -276 .

  • I. Rengel, A. Friedrich , Vet. Res. Commun. 17 (1993) 421–427.

    Friedrich A. , '' (1993 ) 17 Vet. Res. Commun. : 421 -427 .

  • M.M. Jin, X. Li Jian-ming, X. Yao , Zhongguo Weisheng Jianyan Zazhi 15 (2005) 656–658.

    Yao X. , '' (2005 ) 15 Zhongguo Weisheng Jianyan Zazhi : 656 -658 .

  • T. Grobosch, B. Angelow, L. Schoenberg, D. Lampe , J. Anal. Toxicol. 30 (2006) 281–286.

    Lampe D. , '' (2006 ) 30 J. Anal. Toxicol. : 281 -286 .

  • A. Silowiecki, S. Dudkowska, S. Oddzial , Progress Plant Protect. 44 (2004) 1086–1088.

    Oddzial S. , '' (2004 ) 44 Progress Plant Protect. : 1086 -1088 .

  • A. Jones , Bull. Environ. Contam. Toxicol. 56 (1996) 8–15.

    Jones A. , '' (1996 ) 56 Bull. Environ. Contam. Toxicol. : 8 -15 .

  • P. Berny, T. Buronfosse, G. Lorgue , J. Anal. Toxicol. 19 (1995) 576–580.

    Lorgue G. , '' (1995 ) 19 J. Anal. Toxicol. : 576 -580 .

  • X. Wu, X. Zhang, S. Wang , Ziran Kexueban 28 (2002) 229–231.

    Wang S. , '' (2002 ) 28 Ziran Kexueban : 229 -231 .

  • J. Hintze , NCSS and PASS Number Cruncher Statistical Systems, Kaysville, Utah, 2001; www.ncss.com.

    Hintze J. , '', in NCSS and PASS Number Cruncher Statistical Systems , (2001 ) -.

  • S. Erić, D. Agbaba, S. Vladimirov, D. Živanov-Stakić , J. Planar Chromatogr. 13 (2000) 88–92.

    Živanov-Stakić D. , '' (2000 ) 13 J. Planar Chromatogr. : 88 -92 .

  • Sz. Nyiredy (ed.), Planar Chromatography. A Retrospective View for the Third Millennium, Springer, Budapest, 2001.

    '', in Planar Chromatography. A Retrospective View for the Third Millennium , (2001 ) -.

  • T. Gondová, M. Vincová, K. Flórián , J. Planar Chromatogr. 17 (2004) 156–158.

    Flórián K. , '' (2004 ) 17 J. Planar Chromatogr. : 156 -158 .

  • M. Daszykowski, B. Walczak, D.L. Massart , Chemometr. Intell. Lab. Syst. 56 (2001) 83–92.

    Massart D.L. , '' (2001 ) 56 Chemometr. Intell. Lab. Syst. : 83 -92 .

  • A.K. Jain, M.N. Murty, P.J. Flynn , ACM Computing Surveys, Vol. 31, No. 3, September 1999.

  • R.G. Brereton , Chemometrics: Data Analysis for the Laboratory and Chemical Plant, John Wiley & Sons, New York, 2003, 224–230.

    Brereton R.G. , '', in Chemometrics: Data Analysis for the Laboratory and Chemical Plant , (2003 ) -.

  • C.M. Du, K. Valkó, C. Bevan, D. Reynolds , Anal. Chem. 70 (1998) 4228–4234.

    Reynolds D. , '' (1998 ) 70 Anal. Chem. : 4228 -4234 .

  • K. Valkó, C. Bevan, D. Reynolds , Anal. Chem. 69 (1997) 2022–2029.

    Reynolds D. , '' (1997 ) 69 Anal. Chem. : 2022 -2029 .

  • T. Cserháti, E. Forgács , J. Chromatogr. A 771 (1997) 105–109.

    Forgács E. , '' (1997 ) 771 J. Chromatogr. A : 105 -109 .

  • http://146.107.217.178/vcc?action=alogps

  • C.A. Lipinski, F. Lombardo, B.W. Dominy, P.J. Feeney , Adv. Drug Del. Rev. 23 (1997) 3–25.

    Feeney P.J. , '' (1997 ) 23 Adv. Drug Del. Rev. : 3 -25 .
  • Collapse
  • Expand
Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Dec 2024 51 0 0
Jan 2025 27 0 0
Feb 2025 25 0 0
Mar 2025 51 0 0
Apr 2025 17 0 0
May 2025 2 0 0
Jun 2025 0 0 0