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Hakim Faraji Islamic Azad University Department of Chemistry, Faculty of Science, Science and Research Branch P.O. Box 14515-775 Poonak-Hesarak, Tehran Iran

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Mohamad Saber-Tehrani Islamic Azad University Department of Chemistry, Faculty of Science, Science and Research Branch P.O. Box 14515-775 Poonak-Hesarak, Tehran Iran

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Afshin Mirzaie Islamic Azad University Faculty of Food Science and Technology, Science and Research Branch P.O. Box 14515-775 Poonak-Hesarak, Tehran Iran

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Syed Waqif-Husain Islamic Azad University Department of Chemistry, Faculty of Science, Science and Research Branch P.O. Box 14515-775 Poonak-Hesarak, Tehran Iran

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A novel liquid-phase microextraction method coupled with high-performance thin-layer chromatography (HPTLC) for preconcentration, separation, and determination of six phenolic compounds in water samples has been developed. Target analytes were extracted using microliter volume of 1-undecanol, which floated on the surface of the aqueous sample and was separated on an RP-18 F254 HPTLC plate using a mixture of methanol-water 2:1 (%, v/v) as the mobile phase. The plates were developed vertically up to a distance of 80 mm. The calibration curves were linear in the range of 0.025–4.0 and 0.1–20.0 mg per band, with good coefficient of determinations of 0.9978–0.9991 and 0.9985–0.9995, for phenol (PN), 2-chlorophenol (2-CP), 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), 2,3,4,6-tetrachlorophenol (2,3,4,6-TeCP), and pentachlorophenol (PCP). The limit of detection (LOD) and limit of quantification (LOQ) values of the six investigated compounds were between 8–35 and 25–98 ng per band, respectively. The relative standard deviations for repeatability were between 2.61% and 6.35%. The accuracy of the method was checked by the determination of recovery at three different levels, and varied from 89.21% to 101.74% with RSD% of 2.07–6.73% (n = 3).

  • D. Martinez, E. Pocurull, R.M. Marce, F. Borrull, M. Calull, J. Chromatogr. A 734 (1996) 367–373.

    Calull M. , '' (1996 ) 734 J. Chromatogr. A : 367 -373 .

  • G. Ohlenbusch, M.U. Kumke, F.H. Frimmel, Sci. Total Environ. 253 (2000) 63–74.

    Frimmel F.H. , '' (2000 ) 253 Sci. Total Environ. : 63 -74 .

  • A.B. Mckague, J. Chromatogr. A 208 (1981) 287–293.

    Mckague A.B. , '' (1981 ) 208 J. Chromatogr. A : 287 -293 .

  • H.M. Oliveira, M.A. Segundo, J.L.F.C. Lima, V. Cerda, Talanta 77 (2009) 1466–1472.

    Cerda V. , '' (2009 ) 77 Talanta : 1466 -1472 .

  • W. Wei, X.B. Yin, X.W. He, J. Chromatogr. A1202 (2008) 212–215.

    He X.W. , '' (2008 ) A1202 J. Chromatogr. : 212 -215 .

  • X. Chen, T. Zhang, P. Liang, Y. Li, Microchim. Acta 155 (2006) 415–420.

    Li Y. , '' (2006 ) 155 Microchim. Acta : 415 -420 .

  • G. Tadema, P.H. Batelaan, J. Chromatogr. A 33 (1968) 460–470.

    Batelaan P.H. , '' (1968 ) 33 J. Chromatogr. A : 460 -470 .

  • E. Ragazzi, G. Veronese, J. Chromatogr. 77 (1973) 369–375.

    Veronese G. , '' (1973 ) 77 J. Chromatogr. : 369 -375 .

  • A.C. Martel, S. Zeggane, J. Chromatogr. A 954 (2002) 173–180.

    Zeggane S. , '' (2002 ) 954 J. Chromatogr. A : 173 -180 .

  • E. Psillakis, N. Kalogerakis, Trends Anal. Chem. 22 (2003) 565–574.

    Kalogerakis N. , '' (2003 ) 22 Trends Anal. Chem. : 565 -574 .

  • H. Faraji, J. Chromatogr. A 1087 (2005) 283–288.

    Faraji H. , '' (2005 ) 1087 J. Chromatogr. A : 283 -288 .

  • H.H. Liu, P.K. Dasgupta, Anal. Chem. 68 (1996) 1817–1821.

    Dasgupta P.K. , '' (1996 ) 68 Anal. Chem. : 1817 -1821 .

  • M.R. Khalili Zanjani, Y. Yamini, S. Shariati, J.A. Jonsson, Anal. Chim. Acta 585 (2007) 286–293.

    Jonsson J.A. , '' (2007 ) 585 Anal. Chim. Acta : 286 -293 .

  • H. Faraji, M. Saber Tehrani, S.W. Husain, J. Chromatogr. A 1216 (2009) 8569–8574.

    Husain S.W. , '' (2009 ) 1216 J. Chromatogr. A : 8569 -8574 .

  • I. Baranowska, A. Skotniczna, Chromatographia 39 (1994) 564–568.

    Skotniczna A. , '' (1994 ) 39 Chromatographia : 564 -568 .

  • U.A.Th. Brinkman, G. de Vrifs, J. Chromatogr. 258 (1983) 43–55.

    Vrifs G. , '' (1983 ) 258 J. Chromatogr. : 43 -55 .

  • O. Bund, W. Fischer, H.E. Hauck, J. Planar Chromatogr. 8 (1995) 300–305.

    Hauck H.E. , '' (1995 ) 8 J. Planar Chromatogr. : 300 -305 .

  • L.S. Bark, R.J.T. Graham, J. Chromatogr. 25 (1966) 347–356.

    Graham R.J.T. , '' (1966 ) 25 J. Chromatogr. : 347 -356 .

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation
1988
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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