JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 27: Issue 3
Atomic layer deposition of aluminum-free silica onto patterned carbon nanotube forests in the preparation of microfabricated thin-layer chromatography plates
Authors:
Supriya Kanyal Brigham Young University Department of Chemistry and Biochemistry Provo Utah 84602 USA

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David Jensen Diamond Analytic Orem Utah 84058 USA

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Andrew Dadson Diamond Analytic Orem Utah 84058 USA

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Richard Vanfleet Brigham Young University Department of Physics and Astronomy Provo Utah 84602 USA

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Robert Davis Brigham Young University Department of Physics and Astronomy Provo Utah 84602 USA

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Matthew Linford Brigham Young University Department of Chemistry and Biochemistry Provo Utah 84602 USA

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Pages:
151–156
Online Publication Date:
27 May 2014
Publication Date:
01 Jun 2014
Article Category:
Research Article
DOI:
https://doi.org/10.1556/jpc.27.2014.3.1
Keywords:
TLC; Silica; ALD; Atomic layer deposition; XPS; ToF-SIMS; Normal phase; Amino; Silane
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We describe the direct, conformal, atomic layer deposition (ALD) of silica onto carbon nanotubes (CNTs) in the microfabrication of thinlayer chromatography (TLC) plates. As before, these plates were prepared with zig-zag hedge and channel microstructures, with high aspect ratio, porous hedges. After ALD, scanning electron microscopy (SEM) showed an increase in the radius of the CNTs of 8–40 nm. X-ray photoelectron spectroscopy (XPS) showed that the plates were composed almost entirely of silicon and oxygen, without contamination of metals or other elements that might compromise chromatographic performance, e.g., aluminum. Time-of-flight secondary ion mass spectrometry confirmed the extremely low level of aluminum in the plates. The final TLC layer thickness was ca. 50 μm. Separations of a test mixture of dyes from CAMAG (Muttenz, Switzerland) on an uncoated silica plate under traditional, normal phase conditions gave efficiencies of 40,000–140,000 plates m−1 with migration distances ranging from 2 to 36 mm. A separation of two fluorescent dyes, eosin Y disodium salt and sulforhodamine B, on an amino silane-coated plate gave efficiencies of ca. 170,000 and 200,000 plates m−1, with hRF values of 76 and 88, respectively. Run times on these new plates were much faster than on conventional TLC plates.

  • A.P. Boichenko, Open Surf. Sci. J. 1 (2009) 40–45.

    Boichenko A.P. , '' (2009 ) 1 Open Surf. Sci. J. : 40 -45 .

  • S.R. Jim, A.J. Oko, M.T. Taschuk, M.J. Brett, J. Chromatogr. A 1218 (2011) 7203–7210.

    Brett M.J. , '' (2011 ) 1218 J. Chromatogr. A : 7203 -7210 .

  • S.R. Jim, M.T. Taschuk, G.E. Morlock, L.W. Bezuidenhout, W. Schwack, M.J. Brett, Anal. Chem. 82 (2010) 5349–5356.

    Brett M.J. , '' (2010 ) 82 Anal. Chem. : 5349 -5356 .

  • A.J. Oko, S.R. Jim, M.T. Taschuk, M.J. Brett, J. Chromatogr. A 1218 (2011) 2661–2667.

    Brett M.J. , '' (2011 ) 1218 J. Chromatogr. A : 2661 -2667 .

  • S. Eeltink, F. Svec, J.M.J. Frechet, Electrophoresis 27 (2006) 4249–4256.

    Frechet J.M.J. , '' (2006 ) 27 Electrophoresis : 4249 -4256 .

  • Y.H. Han, P. Levkin, I. Abarientos, H.W. Liu, F. Svec, J.M.J. Frechet, Anal. Chem. 82 (2010) 2520–2528.

    Frechet J.M.J. , '' (2010 ) 82 Anal. Chem. : 2520 -2528 .

  • R. Bakry, G.K. Bonn, D. Mair, F. Svec, Anal. Chem. 79 (2007) 486–493.

    Mair D. , '' (2007 ) 79 F. Svec, Anal. Chem. : 486 -493 .

  • I. Urbanova, F. Svec, J. Sep. Sci. 34 (2011) 2345–2351.

    Urbanova I. , '' (2011 ) 34 F. Svec, J. Sep. Sci. : 2345 -2351 .

  • C.L. Shao, H. Kim, J. Gong, D. Lee, Nanotechnology 13 (2002) 635–637.

    Lee D. , '' (2002 ) 13 Nanotechnology : 635 -637 .

  • J.E. Clark, S.V. Olesik, J. Chromatogr. A 1217 (2010) 4655–4662.

    Olesik S.V. , '' (2010 ) 1217 J. Chromatogr. A : 4655 -4662 .

  • D.S. Jensen, S.S. Kanyal, V. Gupta, M.A. Vail, A.E. Dadson, M. Engelhard, R. Vanfleet, R.C. Davis, M.R. Linford, J. Chromatogr. A 1257 (2012) 195–203.

    Linford M.R. , '' (2012 ) 1257 J. Chromatogr. A : 195 -203 .

  • D.S. Jensen, S.S. Kanyal, N. Madaan, A.J. Miles, R.C. Davis, R. Vanfleet, M.A. Vail, A.E. Dadson, M.R. Linford, J. Vac. Sci. Tech. B 31 (2013) 031803(1)–031803(8).

    Linford M.R. , '' (2013 ) 31 J. Vac. Sci. Tech. B : 031803(1) -031803(8) .

  • D.S. Jensen, S.S. Kanyal, N. Madaan, J.M. Hancock, A.E. Dadson, M.A. Vail, R. Vanfleet, V. Shutthanandan, Z.H. Zhu, M.H. Engelhard, M.R. Linford, Surf. Interface Anal. 45 (2013) 1273–1282.

    Linford M.R. , '' (2013 ) 45 Surf. Interface Anal. : 1273 -1282 .

  • J. Song, D.S. Jensen, D.N. Hutchison, B. Turner, T. Wood, A. Dadson, M.A. Vail, M.R. Linford, R.R. Vanfleet, R.C. Davis, Adv. Funct. Mater. 21 (2011) 1132–1139.

    Davis R.C. , '' (2011 ) 21 Adv. Funct. Mater. : 1132 -1139 .

  • H.S. Yang, M.S. Bakir, Ieee T. Comp. Pack. Man. 2 (2012) 561–568.

    Bakir M.S. , '' (2012 ) 2 Ieee T. Comp. Pack. Man. : 561 -568 .

  • A. Hierlemann, O. Brand, C. Hagleitner, H. Baltes, Proc. IEEE 91 (2003) 839.

    Baltes H. , '' (2003 ) 91 Proc. IEEE : 839 -.

  • M.S. Talary, J.P.H. Burt, R. Pethig, Parasitology 117 (1998) S191–S203.

    Pethig R. , '' (1998 ) 117 Parasitology : S191 -S203 .

  • A.V. Govindarajan, S. Ramachandran, G.D. Vigil, P. Yager, K.F. Bohringer, Lab Chip 12 (2012) 174–181.

    Bohringer K.F. , '' (2012 ) 12 Lab Chip : 174 -181 .

  • H. Becker, L.E. Locascio, Talanta 56 (2002) 267–287.

    Locascio L.E. , '' (2002 ) 56 Talanta : 267 -287 .

  • B.A. Peeni, M.L. Lee, A.R. Hawkins, A.T. Woolley, Electrophoresis 27 (2006) 4888–4895.

    Woolley A.T. , '' (2006 ) 27 Electrophoresis : 4888 -4895 .

  • H.R. Li, Y. Yu, S.F. Dana, B. Li, C.Y. Lee, L.F. Kang, J. Drug Targeting 21 (2013) 611–629.

    Kang L.F. , '' (2013 ) 21 J. Drug Targeting : 611 -629 .

  • P. DelNero, Y.H. Song, C. Fischbach, Biomed. Microdevices 15 (2013) 583–593.

    Fischbach C. , '' (2013 ) 15 Biomed. Microdevices : 583 -593 .

  • E. Nuxoll, Advanced Drug Delivery Reviews 65 (2013) 1611–1625.

    Nuxoll E. , '' (2013 ) 65 Advanced Drug Delivery Reviews : 1611 -1625 .

  • F. Zhang, K. Sautter, A.M. Larsen, D.A. Findley, R.C. Davis, H. Samha, M.R. Linford, Langmuir 26 (2010) 14648–14654.

    Linford M.R. , '' (2010 ) 26 Langmuir : 14648 -14654 .

  • N. Madaan, S.S. Kanyal, D.S. Jensen, M.A. Vail, M. Engelhard, M.R. Linford, Surf. Sci. Spectra 20 (2013) 49–54.

    Linford M.R. , '' (2013 ) 20 Surf. Sci. Spectra : 49 -54 .

  • N. Madaan, S.S. Kanyal, D.S. Jensen, M.A. Vail, M. Engelhard, M.R. Linford, Surf. Sci. Spectra 20 (2013) 36–42.

    Linford M.R. , '' (2013 ) 20 Surf. Sci. Spectra : 36 -42 .

  • N. Madaan, S.S. Kanyal, D.S. Jensen, M.A. Vail, M. Engelhard, M.R. Linford, Surf. Sci. Spectra 20 (2013) 43–48.

    Linford M.R. , '' (2013 ) 20 Surf. Sci. Spectra : 43 -48 .

  • N. Madaan, S.S. Kanyal, D.S. Jensen, M.A. Vail, M. Engelhard, M.R. Linford, Surf. Sci. Spectra 20 (2013) 49–54.

    Linford M.R. , '' (2013 ) 20 Surf. Sci. Spectra : 49 -54 .

  • D.S. Jensen, S.S. Kanyal, N. Madaan, M.A. Vail, M. Engelhard, M.R. Linford, Surf. Sci. Spectra 20 (2013) 62–67.

    Linford M.R. , '' (2013 ) 20 Surf. Sci. Spectra : 62 -67 .

  • S.S. Kanyal, D.S. Jensen, A.J. Miles, A.E. Dadson, M.A. Vail, R.E. Olsen, S. Fabien, J. Nichols, R. Vanfleet, R. Davis, M.R. Linford, J. Vac. Sci Technol. B 31 (2013) 031203.

    Linford M.R. , '' (2013 ) 31 J. Vac. Sci Technol. B : 031203 -.

  • T. Hatanpaa, M. Ritala, M. Leskela, Coord. Chem. Rev. 257 (2013) 3297–3322.

    Leskela M. , '' (2013 ) 257 Coord. Chem. Rev. : 3297 -3322 .

  • D.J.H. Emslie, P. Chadha, J.S. Price, Coord. Chem. Rev. 257 (2013) 3282–3296.

    Price J.S. , '' (2013 ) 257 Coord. Chem. Rev. : 3282 -3296 .

  • M. Mauss, H. Engelhardt, J. Chromatogr. A 371 (1986) 235–242.

    Engelhardt H. , '' (1986 ) 371 J. Chromatogr. A : 235 -242 .

  • L.T. Zhuravlev, Colloids Surf. A 173 (2000) 1–38.

    Zhuravlev L.T. , '' (2000 ) 173 Colloids Surf. A : 1 -38 .

  • F. Grossmann, V. Ehwald, C.D. von Hohenesche, K.K. Unger, J. Chromatogr. A 910 (2001) 223–236.

    Unger K.K. , '' (2001 ) 910 J. Chromatogr. A : 223 -236 .

  • L.T. Zhuravlev, React. Kinet. Catal. Lett. 50 (1993) 15–25.

    Zhuravlev L.T. , '' (1993 ) 50 React. Kinet. Catal. Lett. : 15 -25 .

  • V. Gupta, H. Ganegoda, M. Engelhard, J. Terry, M.R. Linford, J. Chem. Educ. 91 (2013) 232–238.

    Linford M.R. , '' (2013 ) 91 J. Chem. Educ. : 232 -238 .

  • S.K. Poole, C.F. Poole, J. Chromatogr. A 1218 (2011) 2648–2660.

    Poole C.F. , '' (2011 ) 1218 J. Chromatogr. A : 2648 -2660 .

  • L. Yang, N. Shirahata, G. Saini, F. Zhang, L. Pei, M.C. Asplund, D.G. Kurth, K. Ariga, K. Sautter, T. Nakanishi, V. Smentkowski, M.R. Linford, Langmuir 25 (2009) 5674–5683.

    Linford M.R. , '' (2009 ) 25 Langmuir : 5674 -5683 .
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Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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