In our previous papers, we defined layer (planar) dielectrochromatography and we presented its fundamentals (theoretical aspects) such as the displacement of dielectric liquids under nonuniform external alternating electric fields (dielectroosmotic flow [DEOF] effect), the displacement of solute particles or polarized granules (dielectrophoresis [DEP] effect) in electric fields generated by armatures, the theoretical evaluation of the electric intensity generated in the stratified dielectrics, etc. Ready-to-use plates of alumina, silica gel, and cellulose were used for experiments. The obtained results have encouraged us to create our own TLC plates based on alumina enriched with compounds of high dielectric constants like barium sulfate, barium titanate, and titanium dioxide. In this paper, we present the preparation of seven plates containing increasing amounts (1, 2, 3, 4, 6, 8, 10) g of barium titanate in 35 g alumina, the methodology used in their characterization, as well as the obtained results and the perspectives of using this ingredient.
Sz. Nyiredy , in: “Planar Chromatography. A Retrospective View for the Third Millennium,” Springer, Budapest, 2001, pp. 177–199.
E. Mincsovics , K. Ferenczi-Fodor, E. Tyihák, in: J. Sherma and B. Fried (eds.), Handbook of Thin-Layer Chromatography, 3rd edition, Marcel Dekker Inc., New York, 2003, pp. 175–205.
E. Tyihák , E. Mincsovics, J. Planar Chromatogr. 23 (2010) 382–395.
E. Tyihák , E. Mincsovics, Nat. Prod. Commun. 6 (2011) 719–732.
V. Pretorius , B.J. Hopkins, J.D. Schieke, J. Chromatogr. 99 (1974) 23–30.
I. Malinowska , J.K. Rózylo, J. Planar Chromatogr. 11 (1998) 411–414.
St. Kreibik , V. Coman, C. Marutoiu, Gh. Mihailescu, J. Planar Chromatogr. 14 (2001) 246–251.
V. Coman , St. Kreibik, M. Vlassa, J. Planar Chromatogr. 21 (2008) 373–378.
V. Coman , St. Kreibik, C. Tudoran, O. Opris, F. Copaciu, J. Planar Chromatogr. 25 (2012) 504–508.
E. Barrado , J.A. Rodríguez, J. Chromatogr. A 1128 (2006) 189–193.
S. Fuentes , R.A. Zárate, E. Chávez, P. Muñoz, M. Ayal, R. Espinoza-Gonzáles, P. Leyton, J. Alloys Compd. 505 (2010) 568–572.
I.J. Lin , L. Benguigui, Coal Gold Base Min. South. Afr. 30 (1982) 45–56.
V. Coman , St. Kreibik, in: E. Tyihák (ed.), Forced Flow Layer Chromatography, Ch. 5, Elsevier, Amsterdam, 2015, e-print, pp. 285–345.
H.A. Pohl , Dielectrophoresis. The Behavior of Neutral Matter in Nonuniform Electric Fields, Cambridge University Press, Cambridge, 1978.
T.B. Jones , Electromechanics of Particles, Cambridge University Press, Cambridge, 1995.
E. Stahl , Thin-Layer Chromatography. A Laboratory Handbook. Springer-Verlag, Berlin, 1969.
J.C. Touchstone , M.F. Dobbins, Practice of Thin Layer Chromatography, John Wiley & Sons, New York, 1978, pp. 18–20, 27.
Al. Nicula , F. Puskas, Dielectrics and Feroelectrics, Scrisul Românesc Publishing House, Craiova, 1982, pp. 81–94.
E. Chávez , S. Fuentes, R.A. Zarate, L. Padilla-Campos, J. Mol. Struct. 984 (2010) 131–136.
W.L. Zhong , Y.G. Wang. P.L. Zhang, B.D. Qu, Phys. Rev. B 50 (1994) 698–703.
H.-J. Feng , F.-M. Liu, Materials Science (cond-mat.mtrl-sci), Apr 23 2007, http://arxiv.org/pdf/0704.2695, 7 pages. Influence of Barium Titanate over V-LDEC Separation 58 Journal of Planar Chromatography 29 (2016) 1
T. Shirai , H. Watanabe, M. Fuji, M. Takahashi, J. Nagoya Inst. Tech.–Ceram. Res. Lab. 9 (2009) 23–31.
S.O. Nelson , T.-S. You, J. Phys. D: Appl. Phys. 23 (1990) 346–353.
CRC Handbook of Chemistry and Physics, CRC Press, Inc., Boca Raton, FL, 1981–1982 Edition.
P.V. Atkins , Handbook of Physical Chemistry, 5th edition, Oxford University Press, Oxford, Melbourne, Tokyo, 1994.
St. Kreibik , V. Coman, C. Marutoiu, Gh. Mihailescu, S. Pruneanu, J. Planar Chromatogr. 14 (2001) 355–359.
R. Plamondon , S. Gagné, IEEE Trans. Biomed. Eng. BME 31 (1984) 512–519.
V. Coman , St. Kreibik, J. Planar Chromatogr. 16 (2003) 338–346.
K. Bauer , L. Gros, W. Sauer, Thin Layer Chromatography. An Introduction, Hüthig, Heidelberg, 1991.
E. Reich , A. Schibli, J. Planar Chromatogr. 17 (2004) 438–443.
J.J. Bikerman , Surface Chemistry. Theory and Applications, 2nd edition, Academic Press Inc. Publishers, New York, 1958, pp. 347.
S.J. Gregg , K.S.W. Sing, Adsorption, Surface Area and Porosity, Academic Press, London, New York, 1967, pp. 140–189.
V.R. Meyer , Practical High Performace Liquid Chromatography, John Wiley & Sons, Chichester, New York, 1998, pp. 23.
K. Robards , P.R. Haddad, P.E. Jackson, Principles and Practice of Modern Chromatographic Methods, Elsevier –Academic Press, Amsterdam, New York, 2004, pp. 49–64.
C. Liteanu , S. Gocan, T. Hodisan, H. Nascu, Liquid Chromatography (Cromatografia de lichide), Scientific Publishing House, Bucharest, 1974, pp. 18–27.