JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 29: Issue 5
Characterization of phenolic compounds contained in bio-oil stemming from agricultural biomass wastes
Authors:
Sebastián Vecino Mantilla Universidad Industrial de Santander, Carrera 27, Calle 9 Ciudadela Universitaria, Bucaramanga, Colombia

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Álvaro Mancilla Manrique Universidad Industrial de Santander, Carrera 27, Calle 9 Ciudadela Universitaria, Bucaramanga, Colombia

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Paola Gauthier-Maradei Universidad Industrial de Santander, Carrera 27, Calle 9 Ciudadela Universitaria, Bucaramanga, Colombia

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Pages:
361–365
Online Publication Date:
Oct 2016
Publication Date:
01 Oct 2016
Article Category:
Research Article
DOI:
https://doi.org/10.1556/1006.2016.29.5.6
Keywords:
Thin-layer chromatography; Phenol; Bio-oil; Characterization
Restricted access

Bio-oil is produced by biomass pyrolysis. It contains hundreds of chemical compounds including alkanes, aromatic hydrocarbons, esters, ethers, ketones, aldehydes, acids, alcohols, and phenols. Phenols are compounds of increasing interest; they can be used as feedstock in many industrial applications such as the production of fuel additives, chemical synthesis, or as food antioxidants. Therefore, the valorization of phenols stemming from bio-oil can be an appropriated alternative to reduce the dependence on petro-based phenols in the chemical industry. The most important phenols in biooil from agricultural wastes are phenol, guaiacol, cresols, syringol, and xylenol. These compounds were separated by silica gel column chromatography technique, using 3 different solvents: a dichloromethane—acetone mixture, ethyl acetate, and methanol. Column elution was followed by thin-layer chromatography (TLC). Phenolic fraction was obtained and not individual phenols. This fraction was analyzed using gas chromatography–flame ionization detector (GC—FID) and gas chromatography—gas chromatography—mass spectrometry (GC—MS) with a DB-1701 column, and it was quantified using the relative response factor. Dichloromethane—acetone mixture was the best eluent to obtain this phenolic fraction, specifically during the first three elution steps.

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Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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