JPC - Journal of Planar Chromatography - Modern TLC
Volume/Issue:
Volume 30: Issue 2
Liquid chromatography with room temperature ionic liquids
Authors:
Nicole Lenca Wayne State University, Detroit, MI 48202, USA

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and
Colin F. Poole Wayne State University, Detroit, MI 48202, USA

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Pages:
97–105
Online Publication Date:
Apr 2017
Publication Date:
01 Apr 2017
Article Category:
Review Article
DOI:
https://doi.org/10.1556/1006.2017.30.2.2
Keywords:
Room temperature ionic liquids; Liquid chromatography; Planar chromatography; Mobile phases; Additives; Solvation parameter model; Solvent classification
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Room temperature ionic liquids are a new class of solvents of potential interest for liquid chromatography. Ionic liquids possess a combination of physical and solvation properties that are complementary to conventional organic solvents. Applications in liquid chromatography are currently limited by their unfavorable viscosity and low-wavelength absorption in the ultraviolet (UV) region. In addition, for planar chromatography, the absence of a vapor pressure does not allow evaporation of ionic liquid solvents after development. The room temperature ionic liquids are good solvents for nonionic compounds with a different blend of intermolecular interactions compared with conventional organic solvents as indicated by solvatochromic measurements and the system constants of the solvation parameter model. Current applications in column and planar chromatography are reviewed to demonstrate the potential of room temperature ionic liquids as mobile phases or mobile phase additives in separation science. A real breakthrough in their use, however, requires the identification of new room temperature ionic liquids with viscosity closer to those of conventional organic solvents as well as addressing other minor issues described in the text.

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Cover JPC - Journal of Planar Chromatography - Modern TLC
JPC - Journal of Planar Chromatography - Modern TLC
Print ISSN:
0933-4173
Online ISSN:
1789-0993

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Manuscript Submission: HERE

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Journal of Planar Chromatography - Modern TLC
Language English
Size A4
Year of
Foundation		 1988
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0933-4173 (Print)
ISSN 1789-0993 (Online)

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