View More View Less
  • 1 Regional Forensic Science Laboratories, Aurangabad, MS, India
  • 2 Dr Babasahab Ambadker Marathwada University, Aurangabad, MS, India
  • 3 Home Department, State of Maharashtra, Vidyanagari, Kalina, Hans Bhugra Road, Santa Cruz (E), Mumbai 400098, India
  • 4 Sant Ramdas College Ghansawangi, Jalna, MS, India
Restricted access

Summary

A novel chromogenic reagent was developed for the identification and detection of organophosphorus herbicide. The organophosphorus herbicide glyphosate is abundantly used, despite being highly toxic to human beings. In the presented communication, we have developed a simple identification and detection technique for the identification of organophosphorus herbicides with the help of thin-layer chromatography. By using this technique, we can easily identify the presence of organophosphorus poisoning by the use of cobalt thiocyanate. By using the cobalt thiocyanate reagent, we can easily identify color change by high-performance thin-layer chromatography (HPTLC). We developed a simple HPTLC method for testing forensic samples. The results obtained are highly useful in the field of organic qualitative analysis, chemistry, forensic science, and toxicology.

  • [1]

    S.O. Duke , S.B. Powles, Pest Manag. Sci. 64 (2008) 319325.

  • [2]

    A. Székács , B. Darvas, InTech Open Access (2012) 247284; DOI: 10.5772/32491.

  • [3]

    G.M. Dill , R.D. Sammons, P.C.C. Feng, F. Kohn, K. Kretzmer, A. Mehrsheikh, M. Bleeke, J.L. Honegger, D. Farmer, D. Wright, E.A. Haupfear, in V.K. Nandula (ed.), Glyphosate Resistance in Crops and Weeds: History, Development, and Management, Wiley, Hoboken, NJ, 2010, pp. 133.

    • Search Google Scholar
    • Export Citation
  • [4]

    C.D.S. Tomlin (ed.), The Pesticide Manual, 11th edn., The British Crop Protection Council, Brighton, 1997, pp. 646649.

  • [5]

    U.D. Pawar , U.K. Kulkarni, H.A. Deshpande, R.K. Pardeshi, World J. Pharm. Pharm. Sci. 6 (2017) 972978.

  • [6]

    E.G.C. Clarke , Isolation and Identification of Drugs, 3rd edn., Vol. I, Pharmaceutical Press, London, 2004, p. 284.

  • [7]

    E.G.C. Clarke , Isolation and Identification of Drugs, 3rd edn., Vol. I, Pharmaceutical Press, London, 2004, p. 287.

  • [8]

    J.A. Morris , J. Forensic Sci. 52 (2007) 8487.

  • [9]

    R. Haddoub , D. Ferry, P. Marsal, O. Siri, New J. Chem. 35 (2011) 13511354.

  • [10]

    S.R. Kote , M.R. Bhandarkar, N.L. Chutke, J. Planar Chromatogr. 28 (2015) 352353.

  • [11]

    M.G. Cikalo , D.M. Goodall, W. Matthews, Chromatogr. A 745 (1996) 189200.

  • [12]

    S.Y. Chang , C.H. Liao, J. Chromatogr. A 959 (2002) 309315.

  • [13]

    L. Goodwin , J.R. Startin, B.J. Keely, D.M. Goodall, J. Chromatogr. A 1004 (2003) 107119.

  • [14]

    Y. Zhu , F. Zhang, C. Tong, W. Liu, J. Chromatogr. A 850 (1999) 297301.

  • [15]

    M.P. Abdullah , J. Daud, K.S. Hong, C.H. Yew, J. Chromatogr. A 697 (1995) 363369.

  • [16]

    E. Mallat , D. Barcelo, J. Chromatogr. A 823 (1998) 129136.

  • [17]

    J. Patsias , A. Papadopoulou, E. Papadopoulou-Mourkidou, J. Chromatogr. A 932 (2001) 8390.

  • [18]

    H. Kataoka , S. Ryu, N. Sakiyama, M. Makita, J. Chromatogr. A 726 (1996) 253258.

  • [19]

    Z.H. Kudzin , D.K. Gralak, J. Drabowicz, J. Luczak, J. Chromatogr. A 947 (2002) 129141.

  • [20]

    E. Borjesson , L. Torstensson, J. Chromatogr. A 886 (2000) 207216.

  • [21]

    E.A. Lee , L.R. Zimmerman, B.S. Bhullar, E.M. Thurman, Anal. Chem. 74 (2002) 49374943.

  • [22]

    M.A.G. Martinez , E.M. Brun, R. Puchades, A. Maquieira, K. Ramsey, F. Rubio, Anal. Chem. 77 (2005) 42194227.

  • [23]

    T.S.A. Deen , D.B. Hibbert, J.M. Hook, R.J. Wells, Anal. Chim. Acta 474 (2002) 125135.

  • [24]

    K. Sato , J.Y. Jin, T. Takeuchi, T. Miwa, K. Suenami, Y. Takekoshi, S. Kanno, J. Chromatogr. A 919 (2001) 313320.

  • [25]

    U.D. Pawar , C.D. Pawar, U.K. Kulkarni, R.K. Pardeshi, D.B. Shinde, J. Planar Chromatogr. 31 (2018) 405407.

  • [26]

    U.D. Pawar , C.D. Pawar, U.K. Kulkarni, R.K. Pardeshi, M. Farooqui, D.B. Shinde, J. Planar Chromatogr. 32 (2019) 6164.

  • [27]

    U.D. Pawar , C.D. Pawar, U.K. Kulkarni, R.K. Pardeshi, M. Farooqui, D.B. Shinde, J. Planar Chromatogr. 32 (2019) 6568.

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Aug 2020 12 0 0
Sep 2020 10 0 0
Oct 2020 11 0 0
Nov 2020 12 0 0
Dec 2020 9 0 0
Jan 2021 4 0 0
Feb 2021 0 0 0