Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 1: Issue 1
Redoxmethoden mit neutronenaktiviertem Silbermetall (110mAg) als Radioreagenz
Authors:
A. Illaszewicz Technische Hochschule Graz Institut für allgemeine Chemie, Mikro- und Radiochemie Österreich

Search for other papers by A. Illaszewicz in
Current site
Google Scholar
PubMed Close
,
K. Müller Technische Hochschule Graz Institut für allgemeine Chemie, Mikro- und Radiochemie Österreich

Search for other papers by K. Müller in
Current site
Google Scholar
PubMed Close
,
D. Rabussay Technische Hochschule Graz Institut für allgemeine Chemie, Mikro- und Radiochemie Österreich

Search for other papers by D. Rabussay in
Current site
Google Scholar
PubMed Close
, and
H. Spitzy Technische Hochschule Graz Institut für allgemeine Chemie, Mikro- und Radiochemie Österreich

Search for other papers by H. Spitzy in
Current site
Google Scholar
PubMed Close
Pages:
39–49
Online Publication Date:
12 Oct 2006
Publication Date:
17 Jan 1968
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02513580
Restricted access

Abstract  

A new analytical method using metallic silver (110mAg) as radioreagent is reported. A known amount of excess oxidant is applied to the reducing agent which is to be determined. After the reaction has taken place, the excess of the oxidizing agent is reacted with the neutron-activated silver whereby110mAg ions are released. The count rate of the solution is proportional to the excess of the oxidant, thus it is possible to determine the original content of the reducing agent in question. The proposed redox procedure based on back measurements has been applied to determinations of hydrogen peroxide, sodium oxalate, potassium ferrocyanide(II), uranium(IV), as well as hydroquinone and ethanol in the μg range. The method makes use of calibration curves; the standard deviation is ±2% on the average. Necessary heights of the normal potentials of the involved systems, favourable reaction conditions, and kineticsa are discussed.

  • Collapse
  • Expand
Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Dec 2024 0 0 0
Jan 2025 6 0 0
Feb 2025 9 0 0
Mar 2025 10 0 0
Apr 2025 4 0 0
May 2025 3 0 0
Jun 2025 0 0 0