Theoretical calculations of pulse radiolysis spectra of trapped electrons in glassy media

D. Światła; W. Bartczak; J. Kroh

doi:10.1007/bf02042426

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 101: Issue 2

Theoretical calculations of pulse radiolysis spectra of trapped electrons in glassy media

Authors:

D. Światła

D. Światła Technical University (Politechnika) Institute of Applied Radiation Chemistry Wróblewskiego 15 Łódź (Poland)

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W. Bartczak

W. Bartczak Technical University (Politechnika) Institute of Applied Radiation Chemistry Wróblewskiego 15 Łódź (Poland)

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J. Kroh

J. Kroh Technical University (Politechnika) Institute of Applied Radiation Chemistry Wróblewskiego 15 Łódź (Poland)

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Pages:: 257–265

Online Publication Date:: 13 Aug 2005

Publication Date:: 17 Oct 1986

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02042426

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Abstract

Calculations of the absorption spectra of e _t^– were performed using the model of electron localization in amorphous media. The model describes electron localization as the radiationless transition of an electron from the conduction state to the binding level of one of a statistical variety of the pre-existing traps in the matrix. Electron capture by very deep traps is considered as a two-stage process-electron capture by the excited level of the trap followed by relaxation to the ground state. The time evolution and the temperature dependence of the optical absorption spectra of e _t^– were computed for polar and nonpolar glasses. The spectral changes predicted by the model follow the experimental results provided by pulse radiolysis.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)