Characterization of copper hexacyanoferrate(II) and (III) with reference to their use as cesium adsorbers

M. Valentini; R. Stella; M. Cola

doi:10.1007/bf02037951

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 102: Issue 1

Characterization of copper hexacyanoferrate(II) and (III) with reference to their use as cesium adsorbers

Authors:

M. Valentini

M. Valentini Università di Pavia Dipartimento di Chimica Generale Viale Taramelli 12-27100 Pavia Italy

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R. Stella

R. Stella Centro di Radiochimica e Analisi per Attivazione del CNR Dipartimento di Chimica Generale Viale Taramelli 12-27100 Pavia Italy

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, and

M. Cola

M. Cola Università di Pavia Dipartimento di Chimica Generale Viale Taramelli 12-27100 Pavia Italy

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Pages:: 99–110

Online Publication Date:: 13 Aug 2005

Publication Date:: 17 Nov 1986

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02037951

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Abstract

A description is given of the preparation and chemical properties of copper(II) hexacyanoferrate (II) and (III). The first is well known and already used for rapid determination of¹³⁷Cs in a wide variety of matrices, but the survey reveals that copper(II) hexacyanoferrate(III) is preferable as long as adsorption capacity is concerned. Thermal stability, reactions in acid media and competitive adsorption of K⁺ and NH ₄⁺ ions are discussed for both adsorbers.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)