Oxidation of plutonium by cobalt(III) green

N. Gopinath; G. Rao

doi:10.1007/bf02165415

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 104: Issue 1

Oxidation of plutonium by cobalt(III) green

Authors:

N. Gopinath

N. Gopinath Bhabha Atomic Research Centre Fuel Chemistry Division 400 085 Bombay India

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G. Rao

G. Rao Bhabha Atomic Research Centre Fuel Chemistry Division 400 085 Bombay India

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Pages:: 7–12

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Mar 1986

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02165415

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Abstract

A stable green solution of tricarbonatocobaltate(III) has been prepared and used for the redox titrimetric determination of plutonium in HNO₃ medium. Quantitative oxidation could be achieved and excess oxidant could be destroyed by NaNO₂. Pu(VI) was deter-ined by adding known excess of Fe(II) and carrying out potentiometric titration. The precision at the level of 0.5–5.0 mg was 2% RSD.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)