Electrochemical oxidation of californium in carbonae solutions

V. Frenkel; Yu. Kulyako; V. Chistyakov; I. Lebedev; B. Myasoedov; G. Timofeev; E. Erin

doi:10.1007/bf02165322

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 104: Issue 4

Electrochemical oxidation of californium in carbonae solutions

Authors:

V. Frenkel

V. Frenkel Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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Yu. Kulyako

Yu. Kulyako Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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V. Chistyakov

V. Chistyakov Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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I. Lebedev

I. Lebedev Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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B. Myasoedov

B. Myasoedov Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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G. Timofeev

G. Timofeev Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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E. Erin

E. Erin Academy of Sciences of the USSR V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Moscow USSR

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Pages:: 191–199

Online Publication Date:: 20 Sep 2005

Publication Date:: 17 Apr 1986

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02165322

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Abstract

The electrolysis of trivalent californium, terbium and praseodimium in 2M K₂CO₃ solutions at pH 13.2 results in a partial oxidation of the trivalent ions to a higher oxidation state. Absorption spectra of Cf/III/ in 1M HCLO₄ and in 2M K₂O₃ and that of oxidized californium in carbonate solution have been recorded. Incomplete oxidation is accounted to a reducing species generated at high anode potentials.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)