Mössbauer effect studies on sodium hexa/carboxylato/ ferrates/III/

B. Randhawa; D. Chhabra; Sandeep Kaur

doi:10.1007/bf02162815

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 105: Issue 1

Mössbauer effect studies on sodium hexa/carboxylato/ ferrates/III/

Authors:

B. Randhawa

B. Randhawa Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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D. Chhabra

D. Chhabra Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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Sandeep Kaur

Sandeep Kaur Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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Pages:: 13–18

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 May 1986

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02162815

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Abstract

Mössbauer spectra of a series of the complexes of the type Na₃[Fe/RCOO/₆]xH₂O /R=H, CH₃, C₂H₅, C₆H₅/ has been recorded at 298±2 K. All display a quadrupole doublet with isomer shift and quadrupole splitting values in agreement with high spin iron/III/ octahedral geometry. The quadrupole splitting show an increasing trend with increasing polarizability of the substituent anion /RCOO^–/. A linear correlation between quadrupole splitting values and the /Fe–O/ stretching frequencies has also been observed.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)