Authors:
B. Randhawa Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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D. Chhabra Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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Sandeep Kaur Guru Nanak Dev University Department of Chemistry 143 005 Amritsar India

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Abstract  

The thermal decomposition of sodium hexa-carboxylato/ferrates/III/ i.e. Na3[Fe/RCOO/6].xH2O /R=H, CH3, C2H5/ has been studied at various temperatures in air employing Mössbauer and infrared spectroscopies and non-isothermal techniques /DTG, DTA, TG/. The thermolysis proceeds without undergoing the formation of any iron/II/ intermediate. The particle size of α-Fe2O3 formed during thermolysis shows an increasing trend with increasing decomposition temperature. At higher temperatures α-NaFeO2 is formed as the ultimate product for all the complexes.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)