Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 107: Issue 2
Ion-molecular reactions of primary radical cations of aliphatic amines in freon matrices
Authors:
V. Belevsky Moscow State University Department of Chemistry 119899 Moscow USSR

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L. Bugaenko Moscow State University Department of Chemistry 119899 Moscow USSR

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O In Quan Moscow State University Department of Chemistry 119899 Moscow USSR

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Pages:
67–80
Online Publication Date:
27 Sep 2005
Publication Date:
17 Nov 1986
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02163443
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Abstract  

ESR spectra for -irradiated, at –196 °C, solution of Me2NH, Me3N, and EtNH2 in CFCl3 /0.05÷100% amine/ have been studied. Radical cations Me2NH+., Me3N+. and EtNH 2+. were trapped in dilute solutions /less than 1% amine in CFCl3/. The yields of radical cations decrease and those of neutral radicals /Me2 N, CH2NMe2, Et NH/ correspondingly increase as the amine concentration increases. Radical cations Me2NH+. are transformed to Me2 N as well as Me3N+. to C H2NMe2 via proton transfer reaction, which is described by the reaction volume model.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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