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  • 1 Slovak Technical University Central Laboratory of Chemical Technics Jánska 1 81237 Bratislava Czechoslovakia
  • | 2 Slovak Technical University Department of Environmental Chemistry and Technology Jánska 1 812 37 Bratislava Czechoslovakia
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Abstract  

The theoretical error of both the CVC and VCC variants at non-quantitative complex forming reaction M+LML has been studied. The erros of analysis for the following analytical curve determinations are considered: (1) measurement with constant error of the analytical function, (2) measurement with registration of a constant number of disintegrations, (3) measurement at constant time of radioactivity measurement of isolated products. Conditions of isoconcentration point existence are determined. Intervals of parameters at which the relative error of the analysis result is comparable with that of the analytical curve are found out. The optimal conditions of analysis are discussed. Errors of both the CVC and VCC variants are compared with that of the CCV variant. Graphs of the theoretical error of analysis are given. The sub-super equivalent isotope dilution method (SSE IDA) has seven basic variants which can be classified by the CCV, CVC, VCC, VVC, VCV, CVV and VVV codes. The theroretical error of the CCV variant was studied earlier. In the present work, a study of errors of both the CVC and VCC variants is performed and extended to radioactivity measurement regimes that can be easily automated. The radioactive background of measurements is taken into account. Previous results and conclusions are corrected. Erros of both the CVC and VCC variants are compared with that of the CCV variant.

Manuscript Submission: HERE

  • Impact Factor (2019): 1.137
  • Scimago Journal Rank (2019): 0.360
  • SJR Hirsch-Index (2019): 65
  • SJR Quartile Score (2019): Q3 Analytical Chemistry
  • SJR Quartile Score (2019): Q3 Health, Toxicology and Mutagenesis
  • SJR Quartile Score (2019): Q2 Nuclear Energy and Engineering
  • SJR Quartile Score (2019): Q3 Pollution
  • SJR Quartile Score (2019): Q3 Public Health, Environmental and Occupational Health
  • SJR Quartile Score (2019): Q3 Radiology, Nuclear Medicine and Imaging
  • SJR Quartile Score (2019): Q3 Spectroscopy
  • Impact Factor (2018): 1.186
  • Scimago Journal Rank (2018): 0.408
  • SJR Hirsch-Index (2018): 60
  • SJR Quartile Score (2018): Q2 Nuclear Energy and Engineering
  • SJR Quartile Score (2018): Q2 Pollution

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
4
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)