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  • 1 Risø National Laboratory Isotope Division DK-4000 Roskilde (Denmark)
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Abstract  

It has been found that sampling constants vary greatly not only from major elements to trace elements, but also between individual trace elements. A comprehensive investigation of a potential reference material therefore requires the determination of sampling constants for all elements to be certified, and other analytical methods therefore have to be included. For methods in statistical control the described strategy can be applied.