Photochemical reactions of radical-anions $$H_2 S_{\bar 2}^ \cdot $$ in solid phasein solid phase

O. Isaeva; Yu. Razskazovsky; M. Mel'nikov

doi:10.1007/bf02170106

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 117: Issue 5

Photochemical reactions of radical-anions $$H_2 S_{\bar 2}^ \cdot $$ in solid phasein solid phase

Authors:

O. Isaeva

O. Isaeva Moscow State University Department of Chemistry 119899, GSP, V-234 Moscow USSR

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Yu. Razskazovsky

Yu. Razskazovsky Moscow State University Department of Chemistry 119899, GSP, V-234 Moscow USSR

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M. Mel'nikov

M. Mel'nikov Moscow State University Department of Chemistry 119899, GSP, V-234 Moscow USSR

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Pages:: 285–297

Online Publication Date:: 20 Sep 2005

Publication Date:: 17 May 1987

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02170106

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Abstract

Photochemical reactions of radical-anions

\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$H_2 S_{\bar 2}^ \cdot$$ \end{document}

with incident light of 405 and 365 nm were studied quantitatively in matrices of 6M LiCl, 4M CH₃COONa, and C₂H₅OH. the radical-anions were shown to undergo reaction of S–S and S–H bond dissociation. Relative efficiency of the observed processes depends on the energy of incident light, on the nature of matrix, and on the degree of self-association of hydrogen sulphide.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)