Authors:
K. Dhoot University of Jodhpur Department of Physics Jodhpur India

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R. Tripathi University of Jodhpur Department of Physics Jodhpur India

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M. Jangid University of Jodhpur Department of Physics Jodhpur India

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M. Chacharkar Raksha Prayogshala 432 001 Jodhpur India

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Abstract  

Mössbauer spectroscopic studies were carried out on some synthesized iron complexes of Schiff's bases. The studies have evidenced that iron/II/ and iron/III/ species were formed, and no stereoisomers were found. However, the complex of bis/acetylacetone diethylene triamine/ had shown the geometric isomers, and only the Fe/III/ species formed. Immersion of the chelate of iron bis/salicylaldehyde ethylene diamine/ in aerated distilled water for a day had resulted in the conversion of the entire iron/II/ species into the iron/III/ complexes. The exposure to atmosphere had converted a part of iron/II/ into iron/III/ and resulted in distortion of the iron/II/ chelates. This leaves a room to think that oxygen transport or absorption may bring change in the oxidation number of the central metal ion or distortion in the structural arrangements.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)