Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 12: Issue 1
Study of the cocrystallization of nikel ion with magnesium ammonium sulfate using63Ni tracer
Authors:
D. Mahadevappa Department of Post-Graduate Studies and Research in Chemistry Manasagangothri Mysore India

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A. Murthy Department of Post-Graduate Studies and Research in Chemistry Manasagangothri Mysore India

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Pages:
469–474
Online Publication Date:
12 Oct 2006
Publication Date:
01 Oct 1972
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02515339
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Abstract  

The cocrystallization of nickel ammonium sulfate with magnesium ammonium sulfate has been studied at low concentrations of the nickel salt, using radiotracer63Ni. The applicability of the equations developed byBerthelot andNernst, Doerner andHoskins, andAbu Elamayem is discussed. It is concluded that only the logarithmic equation of Doerner-Hoskins holds good for this picromerite system. This reveals that during crystallization the crystals that separate are in momentary equilibrium with the mother liquor and hence the composition of the crystals separating is not homogeneous. Crystallization at higher temperature yields purer crystals of the magnesium salt.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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