Trapping and reactivity of electrons in methanol-isopropanol glasses irradiated at 77 K

S. Kapoor; C. Gopinathan; R. Iyer

doi:10.1007/bf02041753

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 125: Issue 1

Trapping and reactivity of electrons in methanol-isopropanol glasses irradiated at 77 K

Authors:

S. Kapoor

S. Kapoor Bhabha Atomic Research Centre Chemistry Divison 400 085 Bombay (India)

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C. Gopinathan

C. Gopinathan Bhabha Atomic Research Centre Chemistry Divison 400 085 Bombay (India)

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R. Iyer

R. Iyer Bhabha Atomic Research Centre Chemistry Divison 400 085 Bombay (India)

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Pages:: 91–96

Online Publication Date:: 13 Aug 2005

Publication Date:: 17 Nov 1988

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02041753

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Abstract

Mixtures of methanol and isopropanol in a ratio (v/v) varying from 91 to 19 have been gamma-irradiated at 77 K and relative yields of trapped electrons have been measured. The reactivity of the trapped electrons towards acetone and uranyl nitrate has been studied at various methanol isopropanol ratios. On the basis of the results, an attempt has been made to assess the relative importance of the reaction of the electron with the solute prior to trapping with respect to the tunnelling reaction of the trapped electron with the solute.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)