The radiolysis of aqueous solution of bis/1,2-dicarbollyl/cobalt/III/ acid

Ľ. Mátel; Ľ. Vašeková; P. Račay

doi:10.1007/bf02165135

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 126: Issue 5

The radiolysis of aqueous solution of bis/1,2-dicarbollyl/cobalt/III/ acid

Authors:

Ľ. Mátel

Ľ. Mátel Comenius University Department of Nuclear Chemistry 842 15 Bratislava Czechoslovakia

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Ľ. Vašeková

Ľ. Vašeková Comenius University Department of Nuclear Chemistry 842 15 Bratislava Czechoslovakia

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P. Račay

P. Račay Comenius University Department of Nuclear Chemistry 842 15 Bratislava Czechoslovakia

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Pages:: 375–385

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Mar 1988

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02165135

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Abstract

The radiation-induced oxidation of bis/1,2-dicarbollyl/cobalt/III/ acid by OH radicals in deaerated/aerated aqueous solutions has been investigated. 8-Monohydroxy-, and 8,8-dihydroxy-derivatives have been identified as products of the -radiolysis. For the different conditions the following radiationchemical yields were observed: in the presence of N₂ atmosphere G/_OHDCC/=1.58, in aerated solution 2.11 and 3.04 in a solution saturated with CCl₃.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)