Thorium isotopes in seawater are determined by means of adsorption of the Xylenol Orange /XO: H6A/ complex onto XAD-2 resin at pH=3 and the XO concentration of 10–5M, and subsequent purification using an anion-exchange resin, and finally with alpha-spectrometry. The dissolved232Th concentration in the western North Pacific surface water is found to range from 0.8 to 1.2 Bq –1. The adsorbed species of the Th-XO complex under the experimental conditions has a composition of Th/H2A/2 according to the mass balance analysis.