Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 128: Issue 2
Reactions of alkoxy and hydroxy radicals generated photochemically from hydroperoxide molecules
Authors:
G. Móger Central Research Institute for Chemistry of the Hungarian Academy of Sciences P.O.Box 17 H-1525 Budapest Hungary

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G. Irinyi Central Research Institute for Chemistry of the Hungarian Academy of Sciences P.O.Box 17 H-1525 Budapest Hungary

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D. Gál Central Research Institute for Chemistry of the Hungarian Academy of Sciences P.O.Box 17 H-1525 Budapest Hungary

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Pages:
117–123
Online Publication Date:
30 Sep 2005
Publication Date:
17 Sep 1988
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02177008
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Abstract  

In the present work
\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$\dot OH$$ \end{document}
as well as HRO. radicals were generated in the photochemical interaction of 1,2-benzanthracene with
\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$\dot OH$$ \end{document}
radicals were trapped by C6H6. The main reaction of HRO. radicals is hydrogen abstraction from the hydroperoxide group of HROOH. Although OH radicals are less selective, the hydrogen abstraction is the main process during their interaction with aromatics in contrast to reactions in aqueous solutions, where addition to the benzene ring is the rate-determining process in CCl4:
\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$\begin{array}{*{20}c} {k_{\dot OH + HRO\underline {OH} } /k_{\dot OH + \underline {HR} OOH} = 2.5 \pm 0.5 and} \\ {k_{\dot OH + C_6 H_6 } /k_{\dot OH + \underline {HROOH} } = /1.2 \pm 0.15/xlo^{ - 2} .} \\ \end{array}$$ \end{document}
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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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