Authors:
K. Oohashi Chiba University Department of Chemistry, College of Arts and Sciences Yayoi 260 Chiba Japan

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N. Nogawa The University of Tokyo Radioisotope Centre Yayoi 113 Bunkyo-ku, Tokyo Japan

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Y. Tanno The University of Tokyo Radioisotope Centre Yayoi 113 Bunkyo-ku, Tokyo Japan

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N. Morikawa The University of Tokyo Radioisotope Centre Yayoi 113 Bunkyo-ku, Tokyo Japan

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Abstract  

The reactivity of recoil tritium in the T-for-H substitution was studied in mixtures of benzene, hexane, cyclohexane or cyclohexane-d12 with lithium carbonate which were irradiated in a reactor. The relative rates per C–H bond of hexane and cyclohexane to benzene were somewhat less than one third. The H/D isotope effect in cyclohexane was given as 1.14.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)