Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 128: Issue 3
On the reactivity of recoil tritium with organic compounds
Authors: K. Oohashi 2 , N. Nogawa 1 , Y. Tanno 1 , and N. Morikawa 1
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  • 1 The University of Tokyo Radioisotope Centre Yayoi 113 Bunkyo-ku, Tokyo Japan
  • 2 Chiba University Department of Chemistry, College of Arts and Sciences Yayoi 260 Chiba Japan
DOI:
https://doi.org/10.1007/bf02166647
Page Count:
181–188
Publication Date:
17 Oct 1988
Online Publication Date:
27 Sep 2005
Article Category:
Research Article
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Abstract  

The reactivity of recoil tritium in the T-for-H substitution was studied in mixtures of benzene, hexane, cyclohexane or cyclohexane-d12 with lithium carbonate which were irradiated in a reactor. The relative rates per C–H bond of hexane and cyclohexane to benzene were somewhat less than one third. The H/D isotope effect in cyclohexane was given as 1.14.

Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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