Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 13: Issue 2
Über das Auftreten Höherer Selenanmonosulfandisulfonate im Verlauf der Reduktion von Selenit mit SeS3O 62−
Authors:
E. Blasius Institut für Analytische Chemie und Radiochemie der Universität des Saarlandes Saarbrücken BRD

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A. Knöchel Institut für Analytische Chemie und Radiochemie der Universität des Saarlandes Saarbrücken BRD

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Pages:
373–379
Online Publication Date:
12 Oct 2006
Publication Date:
01 Feb 1973
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02513928
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Abstract  

Selenite reacts with SeS3O 62− in acidic solutions forming selenanmonosulfandisulfonates with up to 6 Se-atoms in the chain. Se5S3O 62− and Se6S3O 62− have been detected for the first time. The decomposition causes precipitation of a sulfur/selenium-mixture. For the Se-precipitation giving reactions of SeO 32− with sulfite, S2O 32− , SeSO 32− , SeS2O 62− and SeS3O 62− a universal reaction scheme has been developed, prevailing of the following single steps: formation of monoselenandisulfonates, formation of build-up reagents, formation of higher selenopolythionates, decomposition of the selenopolythionates with the longest chains.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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