Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 13: Issue 2
The application of ion-exchanger foils in the determination of trace amounts of some metals in water by means of the non-dispersive X-ray fluorescence method
Authors:
B. Hołyńska Academy of Mining and Metallurgy Institute of Nuclear Techniques Cracow Poland

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M. Leszko Jagellonian University Institute of Chemistry Cracow Poland

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E. Nahlik Jagellonian University Institute of Chemistry Cracow Poland

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Pages:
401–411
Online Publication Date:
12 Oct 2006
Publication Date:
01 Feb 1973
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02513931
Restricted access

Abstract  

Preliminary enrichment by means of strong acid ion-exchanger foils has been used to determine trace amounts of metals in water. The kinetics of the exchange reaction between the hydrogen ions in the cation-exchanger foil and metal ions in the solution has been studied. The time needed for the attainment of equilibrium and the values of the distribution coefficients have been determined for Fe2+, Zn2+, Pb2+, Ca2+, Cd2+ and Ba2+ ions. The metal contents in the cation-exchanger foil were determined by means of non-dispersive X-ray fluorescence. The feasibility of the method was determined on the examples of Pb, Zn and Cd ions. The method permits trace amounts of these elements to be determined above 0.01 ppm in the solution. No significant matrix effect due to the presence of Ca and Ba was found for concentration in the solution below 60 ppm.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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