Reactions of trapped electrons in methanol-isopropanol glasses irradiated at 77 K

S. Kapoor; C. Gopinathan; R. Iyer

doi:10.1007/bf02041359

Jump to Content

Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 130: Issue 2

Reactions of trapped electrons in methanol-isopropanol glasses irradiated at 77 K

Authors:

S. Kapoor

S. Kapoor Bhabha Atomic Research Centre Chemistry Division 400 085 Bombay India

Search for other papers by S. Kapoor in
Current site
Google Scholar
PubMed

C. Gopinathan

C. Gopinathan Bhabha Atomic Research Centre Chemistry Division 400 085 Bombay India

Search for other papers by C. Gopinathan in
Current site
Google Scholar
PubMed

, and

R. Iyer

R. Iyer Bhabha Atomic Research Centre Chemistry Division 400 085 Bombay India

Search for other papers by R. Iyer in
Current site
Google Scholar
PubMed

View More View Less

Pages:: 409–415

Online Publication Date:: 14 Aug 2005

Publication Date:: 17 Apr 1989

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02041359

Restricted access

Abstract

Trapped electron (e _T^– ) reactivity in methanol-isopropanol glasses irradiated at 77 K has been studied as a function of trap-depth, the variation in the trap depth being achieved by varying the methanol:isopropanol ratio. Benzyl chloride and carbon disulfide have been used as scavengers. In the case of the glasses containing benzyl chloride, the observed yield of the benzyl radical has been correlated with the trapping efficiency of the matrix. The data has been interpreted with the aim of assessing the relative importance of tunnelling in the scavenging of electrons in low temperature glassy matrices.

Save
Cite
Email this content

Share Link

Copy this link, or click below to email it to a friend
Email this content
or copy the link directly:

https://akjournals.com/abstract/journals/10967/130/2/article-p409.xml
The link was not copied. Your current browser may not support copying via this button.

Link copied successfully

Collapse
Expand

Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)