The extraction order of Th(IV), U(VI) and Mo(VI) based on pH0.5 values is Mo(VI)>U(VI)>Th(IV). Quantitative extraction has been observed for U(VI) by mixture of 10% (v/v) LIX 84 and 0.1M dibenzoylmethane at pH 4.2 and by mixture of 10% LIX 84 and 0.05M HTTA in the pH range 5.5–7.3 and for Mo(VI) by 10% LIX 84 from chloride media at pH 1.5. The order of extraction of Mo(VI) from 1N acid solutions is HCl>H2SO4>HNO3>HClO4 and extraction decreases very rapidly with increase in the concentration of HCl as compared to that from H2SO4, HNO3 and HClO4 acid solutions. The diluents C6H6, CCl4 and CHCl2 are found to be superior ton-butyl alcohol and isoamyl alcohol for extraction of Mo(VI). Influence of concentration of different anions on the extraction of U(VI) and Mo(VI) has been studied. Very little extraction has been observed in case of Th(IV) by LIX 84 or its mixtures with other chelating extractants or neutral donors.