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  • 1 Dresden University of Technology Department of Chemistry Mommsenstraße 13 8027 Dresden (GDR)
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Abstract  

The ion mobilities of [211At] At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes [AtI], [AtI2], [Attu]+, [Attu2]+ and [AtItu] existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm3.