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  • 1 Utkal University Department of Chemistry Vani Vihar 751 004 Bhubaneswar (India)
  • 2 Saha Institute of Nuclear Physics Nuclear Chemistry Division Bidhan Nagar 700 064 Calcutta (India)
  • 3 USSR Academy of Sciences Radiochemistry Laboratory, Vernadsky Institute of Geochemistry and Analitical Chemistry Moscow
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Abstract  

Synergism has been observed in the extraction of zirconium(IV) by mixtures of Aliquat 336 or Alamine 336 with a neutral donor TBP from aq. HCl solutions. Although the extractant dependency for Zr(IV) is found to be nearly second power with respect to TBP alone, monosolvate is found to be formed for extraction by its mixture with Aliquat 336 or Almine 336. Quantitative extraction is observed with mixtures at a lower acidity than that with individual extractants. The species formed is tentatively assigned to be Q2ZrCl6. TBP, where

\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$Q{\mathbf{ }} = {\mathbf{ }}R_3 {\mathbf{ }}\mathop N\limits^ + (CH_3 )$$ \end{document}
for Aliquat 336 and
\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$R_3 {\mathbf{ }}\mathop N\limits^ + H$$ \end{document}
for Alamine 336.