Authors:
Y. Watanabe Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya 158 Tokyo Japan

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M. Nakada Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya 158 Tokyo Japan

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K. Endo Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya 158 Tokyo Japan

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H. Nakahara Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya 158 Tokyo Japan

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H. Sano Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya 158 Tokyo Japan

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Abstract  

KX-ray-gated emission Mössbauer spectra of57Co-labelled CoF2 and CoF2.2H2O were measured at room temperature, using the coincidence technique. A difference was found in the relative intensity of57Fe(II)/57Fe(III) between the X-ray-gated and non-gated emission spectra. The results are explained in terms of local radiolytic effects of water of crystallization and the chemical effects associated with the de-excitation processes caused by EC-decay.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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