Mössbauer study of iron/III/ pyropheophytins

H. Hori; K. Kadono; K. Fukuda; H. Inoue; T. Shirai; E. Fluck

doi:10.1007/bf02163553

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 137: Issue 4

Mössbauer study of iron/III/ pyropheophytins

Authors:

H. Hori

H. Hori Keio University Department of Applied Chemistry, Faculty of Science and Technology 3-14-1 Hiyoshi, Yokohama 223 Japan

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K. Kadono

K. Kadono Keio University Department of Applied Chemistry, Faculty of Science and Technology 3-14-1 Hiyoshi, Yokohama 223 Japan

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K. Fukuda

K. Fukuda Keio University Department of Applied Chemistry, Faculty of Science and Technology 3-14-1 Hiyoshi, Yokohama 223 Japan

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H. Inoue

H. Inoue Keio University Department of Applied Chemistry, Faculty of Science and Technology 3-14-1 Hiyoshi, Yokohama 223 Japan

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T. Shirai

T. Shirai Keio University Department of Applied Chemistry, Faculty of Science and Technology 3-14-1 Hiyoshi, Yokohama 223 Japan

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E. Fluck

E. Fluck Gmelin-Institut der Max-Planck-Gesellschaft Varrentrappstrasse 40/42 D-6000 Frankfurt am Main 90 FRG

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Pages:: 277–286

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Nov 1989

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02163553

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Abstract

/Pyropheophytinato a/ iron/III/ chloride [Fe/Pyropheo-a/Cl] and /pyropheophytinato b/ iron/III/ chloride [Fe/Pyropheo-b/Cl] have been prepared and characterized by Mössbauer spectroscopy. The Mössbauer parameters of the iron/III/pyropheophytins are similar to those of iron/III/ porphyrins. A comparison of the quadrupole splittings for the iron/III/ pyropheophytins with those for the iron/III/ pheophytins suggests that the deviations of the cyclopentenone ring and the saturated pyrrole ring from the macrocyclic plane become smaller with the removal of the methoxycarbonyl group.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)