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  • 1 B. A. R. C. Radiochemistry Division 400085 Bombay (India)
  • 2 B. A. R. C. Fuel Chemistry Divison 400085 Bombay India
  • 3 UTEP Department of Chemistry 79968-0513 El-Paso Texas USA
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Abstract  

Several adducts of U(IV) and Th(IV) with 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedione (FOD) as -diketone and a variety of neutral oxodonors were synthesized and characterized by visible spectral, proton magnetic resonance as well as thermogravimetric studies. Adducts with dimethylformamide (DMF) were found to be most volatile, whereas with trioctylphosphine oxide (TOPO) were quite susceptible towards decomposition.