Author:
M. El-Absy Atomic Energy Establishment Isotope Production Laboratory, Nuclear Chemistry Department P.O. 13759 Cairo Egypt

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Abstract  

Adsorption behaviour of the individual tracer ions:134Cs(I),85,89Sr(II),131,133Ba (II),90Y(III),141Ce(III),152,154Eu(III),95Zr(IV),175,181Hf(IV),95Nb(V),60Co(II),115Cd(II),99mTc(VII), and131I(-I) on charcoal impregnated with stannic chloride from Hcl solutions, was investigated. Batch equilibrium distribution coefficients of the respective ions indicated strong anion exchange properties towards impregnated charcoal. The column breakthrough sorption capacity was of the order of 0.62–0.66 meq·g–1 of dry adsorbent. Small chromatographic columns of impregnated charcoal could achieve rapid and quantitative separation procedures in HCl medium. Strongly adsorbed anions such as TcO 4 and I ions could be eluted with NH4SCN and NH4NO2 eluents, respectively.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)