Author: R. Kański 1
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  • 1 University of Warsaw Department of Chemistry A. Žwirki i Wigury 101 02-089 Warsaw Poland
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The chemical effects of the decay of35S incorporated into doubly labelled molecules of primary and secondary butylthiols have been studied. The final products, viz.14C4H9Cl-1 and14C4H9Cl-2 were detected by radiometric method. It has been established that in the gas phase about 60% of primary molecular ions are stabilized in form of butyl chlorides. In presence of the water vapour the yield of butyl chlorides increases to about 90%.