Author: R. Kański 1
View More View Less
  • 1 University of Warsaw Department of Chemistry A. Žwirki i Wigury 101 02-089 Warsaw Poland
Restricted access

Abstract  

The chemical effects of the decay of35S incorporated into doubly labelled molecules of primary and secondary butylthiols have been studied. The final products, viz.14C4H9Cl-1 and14C4H9Cl-2 were detected by radiometric method. It has been established that in the gas phase about 60% of primary molecular ions are stabilized in form of butyl chlorides. In presence of the water vapour the yield of butyl chlorides increases to about 90%.