Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 150: Issue 2
Supported liquid membrane extraction of W(VI) ions using tri-n-octylamine as carrier
Authors:
M. Ashraf Chaudry Pakistan Institute of Nuclear Science & Technology Nilore, Islamabad (Pakistan)

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,
M. Malik Pakistan Institute of Nuclear Science & Technology Nilore, Islamabad (Pakistan)

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, and
M. Ahmad Pakistan Institute of Nuclear Science & Technology Nilore, Islamabad (Pakistan)

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Pages:
383–396
Online Publication Date:
14 Aug 2005
Publication Date:
17 Aug 1991
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02035326
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Abstract  

Study of the extraction of W(VI) ions using supported liquid membrane has been carried out. The carrier used for this metal ion transport, is tri-n-octylamine (TOA) dissolved in xylene. The liquid was supported in microporous polypropylene film. The parameters studied are effect of carrier concentration in the membrane, acid concentrations in the feed solution, concentration of stripping agent on transport of W(VI) ions and of temperature on the transport properties of these supported liquid membranes. The optimum conditions of transport for these metal ions determined are, TOA concentration, 0.66 mol·dm–3 (TOA); HF concentration in the feed solution, 0.01 mol·dm–3 and concentration of NaOH used as stripping agent 2.5 mol·dm–3. The maximum flux and permeability determined under optimum conditions are 3.06·10–5 mol·m–2·s–1 and 8.44·10–11 mol· ·m2·s–1 at 25±2°C and 4.21·10–5 mol·m–2·s–1 and 11.55·10–11 mol·m2·s–1 at 65°C, respectively. The diffusion coefficients for the metal ion carrier complex in the membrane have also been determined. Under the optimum conditions the value for the metal ion carrier complex is 0.14·10–11 mol·m2·s–1. Mechanism of transport and the complex formed in the presence of HF have also been discussed. The transport process involves two carrier amine molecules and two protons.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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