Authors:
and
S. Kulkarni
S. Kulkarni
Nagpur University Department of Chemistry 440 010 Nagpur India
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A. Garg
A. Garg
Nagpur University Department of Chemistry 440 010 Nagpur India
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Abstract
Radiation induced decomposition of solid alkali metal nitrates at room temperature has been studied up to an absorbed dose of 300 kGy. [NO
2–
] increases with absorbed dose. From the kinetic scheme
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$$NO_3^ - \xrightarrow{{{}^k1}}NO_2^ - + 0; O + NO_2^ - \xrightarrow{{{}^k2}}NO_3^ - ;$$
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and
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$$O + NO_3^ - \xrightarrow{{{}^k3}}NO_2^ - + O_2$$
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, rate constants have been evaluated for the overall radiolytic decomposition of alkali metal nitrates. This kinetic scheme is applicable in the low dose range. At higher doses, however, the radiation induced reaction, NO
2–
+1/2 O2
NO
3–
may also contribute. The overall rate constants are 0.13×10–6 (LiNO3), 1.05×10–6 (NaNO3), 10.10×10–6 (KNO3), 9.50×10–6 (RbNO3) and 25.50×10–6 (CsNO3) kGy–1.
NO
3–
may also contribute. The overall rate constants are 0.13×10–6 (LiNO3), 1.05×10–6 (NaNO3), 10.10×10–6 (KNO3), 9.50×10–6 (RbNO3) and 25.50×10–6 (CsNO3) kGy–1.To see the editorial board, please visit the website of Springer Nature.
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| Journal of Radionalytical and Nuclear Chemistry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1968 |
| Volumes per Year |
1 |
| Issues per Year |
12 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 0236-5731 (Print) |
| ISSN | 1588-2780 (Online) |
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