Gas phase chromatography of halides of elements 104 and 105

A. Türler; H. Gäggeler; K. Gregorich; H. Barth; W. Brüchle; K. Czerwinski; M. Gober; N. Hannink; R. Henderson; D. Hoffman; D. Jost; C. Kacher; B. Kadkhodayan; J. Kovacs; J. Kratz; S. Kreek; D. Lee; J. Leyba; M. Nurmia; M. Schädel; U. Scherer; Schimpf; D. Vermeulen; A. Weber; H. Zimmermann; I. Zvara

doi:10.1007/bf02037108

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 160: Issue 2

Gas phase chromatography of halides of elements 104 and 105

Authors:

A. Türler

A. Türler

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H. Gäggeler

H. Gäggeler Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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K. Gregorich

K. Gregorich

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H. Barth

H. Barth Philipps Universität Marburg D-3550 Marburg (Germany)

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W. Brüchle

W. Brüchle Gesellschaft für Schwerionenforschung mbH GSI D-61 Darmstadt (Germany)

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K. Czerwinski

K. Czerwinski

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M. Gober

M. Gober Universität Mainz Institut für Kernchemie D-6500 Mainz (Germany)

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N. Hannink

N. Hannink

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R. Henderson

R. Henderson

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D. Hoffman

D. Hoffman

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D. Jost

D. Jost Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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C. Kacher

C. Kacher

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B. Kadkhodayan

B. Kadkhodayan

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J. Kovacs

J. Kovacs Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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J. Kratz

J. Kratz Universität Mainz Institut für Kernchemie D-6500 Mainz (Germany)

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S. Kreek

S. Kreek

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D. Lee

D. Lee

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J. Leyba

J. Leyba

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M. Nurmia

M. Nurmia

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M. Schädel

M. Schädel Gesellschaft für Schwerionenforschung mbH GSI D-61 Darmstadt (Germany)

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U. Scherer

U. Scherer Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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Schimpf

Schimpf Gesellschaft für Schwerionenforschung mbH GSI D-61 Darmstadt (Germany)

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D. Vermeulen

D. Vermeulen Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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A. Weber

A. Weber Paul Scherrer Institut PSI CH-5232 Villigen (Switzerland)

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H. Zimmermann

H. Zimmermann Universität Mainz Institut für Kernchemie D-6500 Mainz (Germany)

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, and

I. Zvara

I. Zvara Joint Institute for Nuclear Research JINR 141980 Dubna (USSR)

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Pages:: 327–339

Online Publication Date:: 14 Aug 2005

Publication Date:: 17 Jul 1992

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02037108

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Abstract

On-line isothermal gas phase chromatography was used to study halides of²⁶¹104 (T_1/2=65 s) and^262,263105 (T_1/2=34 s and 27 s) produced an atom-at-a time via the reactions²⁴⁸Cm(¹⁸O, 5n) and²⁴⁹Bk(¹⁸O, 5n, 4n), respectively. Using HBr and HCl gas as halogenating agents, we were able to produce volatile bromides and chlorides of the above mentioned elements and study their behavior compared to their lighter homologs in Groups 4 or 5 of the periodic table. Element 104 formed more volatile bromide than its homolog Hf. In contrast, element 105 bromides were found to be less volatile than the bromides of the group 5 elements Nb and Ta. Both 104 and Hf chlorides were observed to be more volatile than their respective bromides.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)