Authors:
S. Matthews Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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A. Boegel Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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S. Eccles Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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S. Homann Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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D. Rice Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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J. Loftis Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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M. Jovanovich Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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R. Caufield Lawrence Livermore National Laboratory P.O. Box 808, Mail Code L-629 94550 Livermore CA USA

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B. Mincher Idaho National Engineering Laboratory P.O. Box 1625 83415-7111 Idaho Falls ID USA

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D. Meikrantz Idaho National Engineering Laboratory P.O. Box 1625 83415-7111 Idaho Falls ID USA

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R. Murphy
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G. Gresham Idaho National Engineering Laboratory P.O. Box 1625 83415-7111 Idaho Falls ID USA

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M. Connoly Idaho National Engineering Laboratory P.O. Box 1625 83415-7111 Idaho Falls ID USA

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Abstract  

The Lawrence Livermore National Laboratory (LLNL) and the Idaho National Engineering Laboratory (INEL) are jointly investigating the decomposition of chlorinated hydrocarbons using bremsstrahlung radiation produced by electron accelerators and gamma photons from spent reactor fuel. Experimental results demonstrate an exponential type decay of concentration with dose for volatile organic compounds (VOCs) in ground water and for both polychlorinated biphenyls (PCBs) and insecticides in organic solutions. Experiments were performed at several photon energies and dose rates with various initial concentrations. Mass balance analysis suggests complete mineralization of VOCs in ground water and indicates significant degradation of PCBs and insecticides to VOC type compounds in organic solutions.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)