Reactions of hole species in γ-irradiated KCl, KBr and KI with the emulsion of aniline and water

L. Bapat; G. Natu; G. Rohokale

doi:10.1007/bf02164263

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 165: Issue 2

Reactions of hole species in γ-irradiated KCl, KBr and KI with the emulsion of aniline and water

Authors:

L. Bapat

L. Bapat N. Wadia College Department of Chemistry 411 001 Pune India

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G. Natu

G. Natu N. Wadia College Department of Chemistry 411 001 Pune India

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G. Rohokale

G. Rohokale N. Wadia College Department of Chemistry 411 001 Pune India

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Pages:: 127–136

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 May 1992

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02164263

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Abstract

-Irradiated KCl, KBr and KI are dissolved separately in the emulsion of water and aniline. Halogens as radiolytic products are extracted in aniline forming stable halogen-aniline complexes. Hole species from V₂ and V₃ centers and free halogens trapped in crystalline salts are solvated first in water phase during dissolution and immediately form complexes with aniline. A typical vibrational structure of absorption bands around 300 nm is observed. The yields of halogens and thereby complexes are found to depend upon the concentration of F and hole centers and the mesh of the salt.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)