Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 166: Issue 1
Pulse radiolysis of ethyl propionate in aqueous solution
Authors:
Á. Bíró Institute of Isotopes of the Hungarian Academy of Sciences P.O.Box 77 H-1525 Budapest Hungary

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and
L. Wojnárovits Institute of Isotopes of the Hungarian Academy of Sciences P.O.Box 77 H-1525 Budapest Hungary

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Pages:
7–14
Online Publication Date:
27 Sep 2005
Publication Date:
17 Sep 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02167993
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Abstract  

Hydrated electrons (e aq– ) formed in water radiolysis react with ethyl propionate with a rate parameter of 7.5×107 mol–1 dm3 s–1. The electron adduct in acidic solutions immediately (<100 ns) dissociates, yielding CH3CH2C=0 radical. This process in alkaline solutions is slower, k=1.4×105 s–1. The hydroxyl radicals abstract H atoms in about 50% from the -position of propionate.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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