Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 166: Issue 2

Reactions of carbonate radical with cobalt(II) aminopolycarboxylates

Authors:
P. Mandal Saha Institute of Nuclear Physics, Sector I, Block Nuclear Chemistry Division AF, Bidhan nagar 700 064 Calcutta India

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D. Bardhan Saha Institute of Nuclear Physics, Sector I, Block Nuclear Chemistry Division AF, Bidhan nagar 700 064 Calcutta India

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S. Bhattacharyya Saha Institute of Nuclear Physics, Sector I, Block Nuclear Chemistry Division AF, Bidhan nagar 700 064 Calcutta India

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Pages:
87–96
Online Publication Date:
27 Sep 2005
Publication Date:
17 Sep 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02169575
Restricted access

Abstract  

Reactions of carbonate (CO 3–· ) and bicarbonate (HCO 3· ) radicals generated by photolysis of a carbonate or bicarbonate solution at pH 11.2 and 8.5, respectively, with Co(II) complexes of iminodiacetic acid (IDA) and ethylenediaminetetraacetic acid (EDTA) have been studied. The rate constants for the reactions were in the order of 106–107 dm3mol–1s–1. From the time-resolved spectroscopy of the products formed after reaction of CO 3·–· or HCO 3· , it is observed that CO 3–· or HCO 3· oxidize the metal center to its higher oxidation state.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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