Photolysis of water-carbon tetrachloride and water-chlorobenzene saturated solutions and their two-phase systems. Quantum yields of chloride ions

J. Kuruc; A. Hlatká

doi:10.1007/bf02164747

Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 166: Issue 3

Photolysis of water-carbon tetrachloride and water-chlorobenzene saturated solutions and their two-phase systems. Quantum yields of chloride ions

Authors:

J. Kuruc

J. Kuruc Comenius University Department of Nuclear Chemistry, Faculty of Natural Sciences CS-84215 Bratislava Slovakia, ČSFR

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A. Hlatká

A. Hlatká Comenius University Department of Nuclear Chemistry, Faculty of Natural Sciences CS-84215 Bratislava Slovakia, ČSFR

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Pages:: 239–250

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Oct 1992

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02164747

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Abstract

The quantum yields of formation of chloride ions were determined in photolysis (=254 nm) of watercarbon tetrachloride organic phase of CCl₄(Cl^–)=0.89±0.04 water-chlorobenzene (_PhCl(Cl^–)=0.137± ±0.005) two-phase systems and saturated aqueous solutions of carbon tetrachloride (_CCl4(Cl^–)=18.9±5.6 and chlorobenzene _PhCl(Cl^–)=0.56±0.03. The quantum yields of chloride ions obtained from these systems are compared with partial radiation yields in the same systems. A mechanism for formation of Cl^– ions is proposed.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)