Authors:
N. Joshi Nagpur University Department of Chemistry 440 010 Nagpur (India)

Search for other papers by N. Joshi in
Current site
Google Scholar
PubMed
Close
and
A. Garg Nagpur University Department of Chemistry 440 010 Nagpur (India)

Search for other papers by A. Garg in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

Double nitrates of Na and K having the composition 2MINO3·LnIII(NO3)3·2H2O(LnIII=Pr, Nd, Sm, Eu, Gd, Tb and Dy) and of Ni and Cu with the composition 3MII(NO3)2·2LnIII(NO3)3·24H2O (LnIII=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb and Dy) have been prepared and their -radiolytic decomposition studied up to 500 kGy. G(NO 2 ) values of K double nitrates at 230 kGy follow the order Dy3+>Pr3+=Nd3+=Sm3+>Tb3+>Eu3+> Gd3+·G(NO 23+ ) for NI double nitrates are higher than those of Cu double nitrates. Variation of G(NO 2 ) with cationic radii and the number of f electrons in lanthanide ion show a minimum at Eu. Thermal decomposition studies of double nitrates were also carried out.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)